This is a repeat of last season's quarter-final, when Juventus avenged their 2015 final defeat at the hands of Barca with a 3-0 aggregate win.
Both sides have begun their respective domestic campaigns with three wins out of three, and they will be expected to occupy the top two spots in Group D after matchday six.
Make sure you don't miss a moment of the action courtesy of our minute-by-minute coverage below.
OFFICIAL LINE UPS
JUVENTUS: Buffon; De Sciglio, Benatia, Barzagli, Sandro; Pjanić, Matuidi, Bentancur; Dybala, Douglas Costa, Higuain
BARCELONA: Ter Stegen; Semedo, Pique, Umtiti, Alba; Busquets, Rakitic, Iniesta; Dembele, Suarez, Messi
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