The two players fought over a spot-kick, during their 2-0 win over Lyon in Ligue 1 on Sunday.
Cavani and Neymar argued over the penalty in the 79th minute, with the Uruguayan eventually taking it, but he missed from 12 yards.
“The penalties are to be struck by a few players, one is Cavani and the other is Neymar,” Emery said.
“It takes a gentleman’s agreement on the ground to hit the penalties.
“Afterwards, we will arrange internally for the penalties that are coming in, because I think both are able to score them, and I want the two to alternate in this exercise.
“If there is no agreement, I will decide. I do not want it to be a problem for us.”
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